Metal complex catalysis

Astakhov Alexander Vladimirovich

Post:

Senior Researcher at the Research Institute "Nanotechnology and New Materials"

Education:

2000-2005: student, Platov South-Russian State Polytechnic University (NPI), Novocherkassk.
2005-2008: postgraduate student, SRSPU (NPI), Novocherkassk.

Qualification:

Engineer in the specialty "Chemical technology of organic substances" (7.06.2005).
Candidate of Chemical Sciences, specialty 02.00.03 "Organic Chemistry" (7.10.2011).

Topic of dissertation research:

Synthesis of 1,2,4-triazolopyrimidines based on reactions of 1-substituted 3,5-diamino-1,2,4-triazoles with 1,3-bioelectrophilic reagents

Professional activity:

2008-2012: leading engineer of SRSPU (NPI).
2009-2010: engineer-technologist of LLC "Khimpostavshchik-Don", Aksai.
2010-2012: assistant of the Department "Technology of Inorganic and Organic Substances" of the SRSPU (NPI).
from 2012 to the present: associate Professor of the Department of "Chemical Technologies" of the SRSPU (NPI).
from 2012 to the present: senior Researcher at the Research Institute "Nanotechnologies and New Materials" of the SRSPU (NPI).

Scientific interests:

Organic chemistry, chemistry of heterocyclic compounds, metal complex catalysis, N-heterocyclic carbenes, quantum chemical calculations

Awards and achievements:

2011-2012: the winner of the program "UMNIK".
2013: the award of the Endowment Fund "Education and Science of the Southern Federal District" "The best young teacher 2013".
2016: winner of the RFBR competition under the program "Mobility of young scientists" (grant 16-33-50151 mol_nr "Synthesis and catalytic activity of nickel complexes with N-heterocyclic carbenes of the 1,2,4-triazole series", 07.2016-12.2016).

Project manager:

2012-2013: Ministry of Science and Education of the Russian Federation, Federal Target Program "Scientific and scientific-pedagogical personnel of innovative Russia for 2009 – 2013", GC No. 14.B37.21.1187 "New recyclizations in the synthesis of condensed 1,2,4-triazole derivatives".
2019-2022: The 2019 contest "Conducting research by scientific groups under the leadership of young scientists" of the Presidential Program of research projects implemented by leading scientists, including young scientists. RF 19-73-100 Development of effective catalysts based on nickel and palladium complexes with N-heterocyclic carbenes (NHC) in carbon-heteroatom bond formation reactions for the synthesis of practically important molecules.

Executor in projects:

2009-2011: Ministry of Science and Education of the Russian Federation, competition No. NK-109P, project P302 "New approaches to the selective synthesis of C-amino-1,2,4-triazoles and their derivatives".
2012-2013: Ministry of Science and Education of the Russian Federation, project 14.B37.21.0827 "Synthesis of high-nitrogen heterocycles: new approaches and solutions".
2013-2014: RFBR, grant 13-03-00253 "New rearrangements in the synthesis of condensed heterocycles based on C-amino-1,2,4-triazoles".
2014-2016: RSF, grant 14-23-00078 "New catalytic systems and processes of selective synthesis and processing of multifunctional organic substances".
2017-2018: RSF, grant 14-23-00078 (extension) "New catalytic systems and processes of selective synthesis and processing of multifunctional organic substances".
2016-2019: RFBR, Grant 16-29-10786 "Catalytic systems based on transition metal complexes with N-heterocyclic carbenes: degradation processes of complexes and their effect on catalytic activity in cross-combination reactions.
2019: RFBR, grant 19-03-01053 "New strategies for the synthesis of functionally substituted N-heterocyclic carbenes and their complexes with transition metals".
2019: RSF, grant 19-73-20085 "Highly efficient catalytic systems for C-H functionalization processes based on transition metal complexes with N-heterocyclic carbenes".

Major publications:

Chernyshev V. M., Astakhov A. V., Chikunov I. E., Tyurin R. V., Eremin D. B., Ranny G. S., Khrustalev V. N. and Ananikov V. P. "Pd and Pt Catalyst Poisoning in the Study of Reaction Mechanisms: What Does the Mercury Test Mean for Catalysis?" ACS Catalysis. 2019, P. 2984-2995.
Chernyshev V. M., Khazipov O. V., Shevchenko M. A., Chernenko A. Y., Astakhov A. V., Eremin D. B., Pasyukov D. V., Kashin A. S. and Ananikov V. P. "Revealing the unusual role of bases in activation/deactivation of catalytic systems: O-NHC coupling in M/NHC catalysis" Chemical Science. 2018, 9, P. 5564-5577.
Khazipov O. V., Shevchenko M. A., Chernenko A. Y., Astakhov A. V., Pasyukov D. V., Eremin D. B., Zubavichus Y. V., Khrustalev V. N., Chernyshev V. M. and Ananikov V. P. "Fast and Slow Release of Catalytically Active Species in Metal/NHC Systems Induced by Aliphatic Amines" Organometallics. 2018, 37, P. 1483-1492.
Astakhov A. V., Suponitsky K. Y. and Chernyshev V. M. "Chlorotrimethylsilane-promoted synthesis of 1,2,4-triazolopyrimidines from 3,5-diamino-1,2,4-triazoles and pentane-2,4-diones" Mendeleev Commun. 2018, 28, P. 439-441.
Astakhov A. V., Khazipov O. V., Chernenko A. Y., Pasyukov D. V., Kashin A. S., Gordeev E. G., Khrustalev V. N., Chernyshev V. M. and Ananikov V. P. "A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki–Heck Reaction" Organometallics. 2017, 36, P. 1981-1992.
Pyatakov D. A., Sokolov A. N., Astakhov A. V., Chernenko A. Y., Fakhrutdinov A. N., Rybakov V. B., Chernyshev V. V. and Chernyshev V. M. "Diversity Oriented Synthesis of Polycyclic Heterocycles through the Condensation of 2-Amino[1,2,4]triazolo[1,5-a]pyrimidines with 1,3-Diketones" J. Org. Chem. 2015, 80, P. 10694-10709.
Chernyshev V. M., Vlasova A. G., Astakhov A. V., Shishkina S. V. and Shishkin O. V. "Reactivity of C-Amino-1,2,4-triazoles toward Electrophiles: A Combined Computational and Experimental Study of Alkylation by Halogen Alkanes" J. Org. Chem. 2015, 80, P. 375-385.
Astakhov A. V., Khazipov O. V., Degtyareva E. S., Khrustalev V. N., Chernyshev V. M. and Ananikov V. P. "Facile Hydrolysis of Nickel(II) Complexes with N-Heterocyclic Carbene Ligands" Organometallics. 2015, 34, P. 5759-5766.

Links to identifiers:

Scopus: 13907465700
ResearcherID: L-8111-2013
ORCID: 0000-0001-6926-8919
e-Library: SPIN-код: 8700-5591

SCOPUS

Shepelenko Konstantin Evgenievich

Post:

Senior Researcher at the Research Institute "Nanotechnology and New Materials"

Education:

2007-2012: faculty of Chemistry, Specialty: Chemist. Teacher of the specialty "chemistry", Southern Federal University, Rostov-on-Don.
2012-2016: postgraduate study of the Research Institute of Physical and Organic Chemistry of the Southern Federal University, Rostov-on-Don.

Qualification:

2017: Candidate of Chemical Sciences, (Organic Chemistry 02.00.03) "Synthesis, photo- and ionochromic properties of rhodamine- and azolyl-substituted indoline-series spiropyrans based on hydroxyisophthalic aldehydes"

Project manager:

2021-2023: RSF 21-73-00058 "New methods of selective functionalization of furan compounds-platforms based on metal-catalyzed C-H and C-C activation reactions" Competition 2021 "Conducting initiative research by young scientists" of the Presidential Program of research projects implemented by leading scientists, including young scientists

Major publications:

Ni/NHC catalysis in C-H functionalization using air-tolerant nickelocene and sodium formate for: In situ catalyst generation Khazipov, O.V., Shepelenko, K.E., Pasyukov, D.V., ...Chernyshev, V.M., Ananikov, V.P. Organic Chemistry Frontiers, 2021, 8(11), p. 2515–2524.
Different effects of metal-NHC bond cleavage on the Pd/NHC and Ni/NHC catalyzed α-arylation of ketones with aryl halides Shepelenko, K.E., Soliev, S.B., Galushko, A.S., Chernyshev, V.M., Ananikov, V.P. Inorganic Chemistry Frontiers, 2021, 8(6), p. 1511–1527.
3-Amino-1,2,4-triazolium salts as NHC-proligands: synthesis and postmodification of a new type of amino-functionalized Pd/NHC complexes Pasyukov, D.V., Chernenko, A.Y., Shepelenko, K.E., ...Khrustalev, V.N., Chernyshev, V.M. Mendeleev Communications, 2021, 31(2), p. 176–178.
Benzothiazolyl substituted spiropyrans with ion-driven photochromic transformation Chernyshev, A.V., Voloshin, N.A., Rostovtseva, I.A., ...Gaeva, E.B., Metelitsa, A.V. Dyes and Pigments, 2020, 178, 108337.
Synthesis and Complex Formation of Rhodamine-Substituted Spirobenzopyranindolines Solov’eva, E.V., Rostovtseva, I.A., Shepelenko, K.E., ...Metelitsa, A.V., Minkin, V.I. Russian Journal of General Chemistry, 2018, 88(5), p. 968–972.

Shevchenko Maxim Alexandrovich

Post:

Senior Researcher at the Research Institute "Nanotechnology and New Materials"

Education:

1999: Rostov State University; higher education in the specialty "Chemist. Teacher".
2003: Rostov State University; Candidate of Chemical Sciences, specialty 02.00.03 - Organic Chemistry.

Qualification:

Candidate of Chemical Sciences, specialty 02.00.03 - Organic Chemistry

Professional activity:

2002 - 2012: Rostov State University, Department of Organic Chemistry; Assistant, Lecturer, Senior Lecturer
2016 - 2019: engineer of the Research Institute "Nanotechnology and New materials".
from 2019 to the present: senior researcher.

Scientific interests:

Organic chemistry, metal complex catalysis, N-heterocyclic carbenes, chemistry of heterocyclic compounds

Project manager:

2022-2023: Project Manager of the RSF 22-23-00304 "Water-soluble M/NHC catalysts based on hydrophilic ligands of the imidazole series" Competition 2021 "Conducting basic scientific research and exploratory scientific research by small individual scientific groups"

Major publications:

Chernyshev V. M., Khazipov O. V., Shevchenko M. A., Chernenko A. Yu., Astakhov A. V., Eremin D. B., Pasyukov D. V., Kashin A. S. and Ananikov V. P. "Revealing the unusual role of bases in activation/deactivation of catalytic systems: O–NHC coupling in M/NHC catalysis", Chem. Sci., 2018, 9, 5564-5577.
Khazipov O. V., Shevchenko M. A., Chernenko A. Yu., Astakhov A. V., Pasyukov D. V., Eremin D. B., Zubavichus Y. V., Khrustalev V. N., Chernyshev V. M., and Ananikov V. P. "Fast and Slow Release of Catalytically Active Species in Metal/NHC Systems Induced by Aliphatic Amines", Organometallics, 2018, 37 (9), pp 1483–1492.
M. A. Shevchenko, Y. N. Tkachenko, A. V. Astakhov, O. V. Khazipov, R. V. Tyurin, D. V. Pasyukov, V. A. Tafeenko, O. A. Kravchenko, V. M. Chernyshev "Palladium-catalyzed synthesis of pyrimido[5',4':3,4]pyrrolo[1,2-f]phenanthridine-12,14(11H,13H)-diones and related compounds", Russ.Chem. Bull., 2018, 67, 1684.
E. B. Tsupak, M. A. Shevchenko "[3,4]-annulated pyrroles 1. Polynuclear heterocyclic systems based on pyrrolo[3,4-d]pyrimidine-2,4-dione", Russ. Chem. Bull., 2006, 55, 2265.
E. B. Tsupak, M. A. Shevchenko, A. F. Pozharskii, Y. N. Tkachenko "Pyrrolopyrimidines. 5. Reaction of 6-Amino-1,3-dimethylpyrrolo[3,4-d]pyrimidine-2,4(1H,3H)-diones with 1,3-Diketones", Chem.Heterocycl. Compd., 2003, 39, 953.

Khazipov Oleg Vladimirovich

Post:

Senior Researcher at the Research Institute "Nanotechnology and New Materials"

Education:

2007: diploma of higher education in the specialty "Chemical technology of fuels and carbon materials".
2015: academic degree of Candidate of Chemical Sciences (physical chemistry 02.00.04).

Qualification:

2015: academic degree of Candidate of Chemical Sciences (physical chemistry 02.00.04)

Scientific interests:

Organometallic chemistry; Homogeneous metal-complex catalysis

Project manager:

2022-2023: Head of the project "Competition 2021 "Conducting fundamental scientific research and exploratory scientific research by small individual scientific groups". RSF 22-23-00308 Development of new methods for generating active catalytic systems from air-stable Ni(II) compounds for cross-combination reactions

Major publications:

V.M. Chernyshev, O.V. Khazipov, M.A. Shevchenko, A.Yu. Chernenko, A.V. Astakhov, D.B. Eremin, D.V. Pasyukov, A.S. Kashin, V.P. Ananikov. Revealing the unusual role of bases in activation/deactivation of catalytic systems: O–NHC coupling in M/NHC catalysis, Chem. Sci., 2018, 9, p.5564-5577.
O.V. Khazipov, M.A. Shevchenko, A.Yu. Chernenko, A.V. Astakhov, D.V. Pasyukov, D.B. Eremin, Y.V. Zubavichus, V.N. Khrustalev, V.M. Chernyshev, V.P. Ananikov. Fast and Slow Release of Catalytically Active Species in Metal/NHC Systems Induced by Aliphatic Amines, Organometallics, 2018, 37, p.1483–1492.
A.V. Astakhov, O.V. Khazipov, A.Y. Chernenko, D.V. Pasyukov, A.S. Kashin, E.G. Gordeev, V.N. Khrustalev, V.M. Chernyshev, V.P. Ananikov. A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki–Heck Reaction, Organometallics, 2017, 36, p.1981-1992.
A.V. Astakhov, O.V. Khazipov, E.S. Degtyareva, V.N. Khrustalev, V.M. Chernyshev, V. P. Ananikov. Facile hydrolysis of nickel(II) complexes with N-heterocyclic carbene ligands, Organometallics, 2015, 34, p.5759–5766
O.V. Khazipov, D.V. Nykytenko, T.V. Krasnyakova, A.N. Vdovichenko, D.A. Fuentes Frias, S.A. Mitchenko. Catalytic etherification of alcohols in Shilov system: C-O versus C-H bond activation, Journal of Molecular Catalysis A: Chemical, 2017, 426, p.490-498
O.V. Khazipov, T.V. Krasnyakovab, D.V. Nikitenko, M.A. Merzlikina, E.V. Khomutova, S.A. Mitchenko. Successive alkylation of PtII by RI to form bis-organoplatinum(IV) derivatives as key steps for cross-electrophile coupling, J. Organomet. Chem., 2018, 867, 333-341
S.A. Mitchenko, O.V. Khazipov, T.V. Krasnyakova. Switching regioselectivity in the sequential iodoplatination of methyl propiolate C-C triple bond by PtIV iodo complexes, J. Organomet. Chem., 2015, 793, p.145-154
S.A. Mitchenko, O.V. Khazipov, E.S. Mitchenko, T.V. Krasnyakova. Formation and thermodynamic stability of novel methyl–vinyl derivatives of PtIV as possible intermediates for Csp³–Csp² cross-coupling, J. Organomet. Chem., 2014, 752, p. 91-99
M.A. Shevchenko, Yu.N. Tkachenko, A.V. Astakhov, O.V. Khazipov, R.V. Tyurin, D.V. Pasyukov, V.A. Tafeenko, O.A. Kravchenko, V.M. Chernyshev. Palladium-catalyzed synthesis of pyrimido [5',4':3,4] pyrrolo [1,2-f]phenanthridine-12,14(11H,13H)-dione and related compounds. Russian Chemical Bulletin, 2018, № 9, 1684-1694
O.V. Khazipov, M.A. Merzlikina, D.V. Nikytenko, E.V. Khomutova, T.V. Krasnyakova, S.A. Mitchenko. Solvent-specific reduction of Na2PtI6 in acetone, Russ. J. Gen. Chem., 2017, 87, p.128-131
A. Mitchenko, O. V. Khazipov, T. V. Krasnyakova New stereoselective Csp²−Csp³ coupling: Catalytic iodomethylation of acetylene with methyl iodide into E-1-iodopropene, Kinet. Catal., 2014, Vol.55, Issue 3, pp. 304-310
V.P. Ananikov, A.S. Kashin, O.V. Hazipov, I.P. Beletskaya, Z.A. Starikova. Highly Selective Catalytic Synthesis of (E,E)-1,4-Diiodobuta-1,3-diene via Atom-Efficient Addition of Acetylene and Iodine: A Versatile (E,E)-1,3-Diene Building Block in Cross-Coupling Reactions. Synlett, 2011, V.14, р. 2021-2024
V.P. Ananikov, O.V. Khazipov, I.P. Beletskaya. 1,4-Diiodo-1,3-dienes: Versatile Reagents in Organic Synthesis. Chemistry – An Asian Journal, 2011, V.6, p. 306-323
S.A. Mitchenko, O.V. Khazipov, E.S. Mitchenko, T.V. Krasnyakova. Formation and thermodynamic stability of novel methyl–vinyl derivatives of PtIV as possible intermediates for Csp³–Csp² cross-coupling. J. Organomet. Chem., 2013, V.752, p. 91-99
S.A. Mitchenko, O.V. Khazipov, T.V. Krasnyakova. Switching regioselectivity in the sequential iodoplatination of methyl propiolate C-C triple bond by PtIV iodo complexes. J. Organomet. Chem., 2014, V.793, p.145-154
T.V. Krasnikova, O.V. Khazipov, S.A. Mitchenko, V.M. Chernyshev. Monograph: Platinum acid complexes in the catalysis of C-C combination reactions: monograph. Novocherkassk: SRSPU (NPI), 2015. – 112 p.

Pasyukov Dmitry Viktorovich

Post:

Junior Researcher at the Research Laboratory

Education:

2014-2018: student, Department of "Technology of Inorganic and Organic substances", specialty "Chemical technology of inorganic substances", SRSPU (NPI).
from 2019 to the present: master's degree, Department of "Chemical Technologies", direction "Chemical technology of organic substances", SRSPU (NPI).

Qualification:

2014-2018: student, Department of "Technology of Inorganic and Organic substances", specialty "Chemical technology of inorganic substances", SRSPU (NPI).
2019 – 2021: master, Department of "Chemical Technologies", direction "Chemical technology of organic substances", SRSPU (NPI).

Professional activity:

2015-2016: laboratory assistant of the Research Institute "Nanotechnology and new materials".
from 2017 to the present: technician of the Research Institute "Nanotechnology new materials".

Scientific interests:

Organic chemistry, metal complex catalysis, N-heterocyclic carbenes, chemistry of heterocyclic compounds

Participation in projects:

2015-2018: RSF, grant 14-23-00078 "New catalytic systems and processes of selective synthesis and processing of multifunctional organic substances", project executor.
2016-2019: RFBR, grant 16-29-10786 "Catalytic systems based on transition metal complexes with N-heterocyclic carbenes: degradation processes of complexes and their effect on catalytic activity in cross-combination reactions, project executor.
2019: RFBR, grant 19-03-01053 "New strategies for the synthesis of functionally substituted N-heterocyclic carbenes and their complexes with transition metals", project executor.

Major publications:

Formation and stabilization of nanosized Pd particles in catalytic systems: Ionic nitrogen compounds as catalytic promoters and stabilizers of nanoparticles Chernyshev, V.M., Khazipov, O.V., Eremin, D.B., Denisova, E.A., Ananikov, V.P. Coordination Chemistry Reviews, 2021, 437, 213860.
Ni/NHC catalysis in C-H functionalization using air-tolerant nickelocene and sodium formate for: In situ catalyst generation Khazipov, O.V., Shepelenko, K.E., Pasyukov, D.V., Chernyshev, V.M., Ananikov, V.P. Organic Chemistry Frontiers, 2021, 8(11), p. 2515–2524.
Catalytic Hydromethoxylation of Acetylene over Pre-Activated K2PdCl4 Krasnyakova, T.V., Nikitenko, D.V., Khazipov, O.V., Mitchenko, S.A. Kinetics and Catalysis, 2020, 61(6), p. 879–885.
Preventing Pd-NHC bond cleavage and switching from nano-scale to molecular catalytic systems: Amines and temperature as catalyst activators Khazipov, O.V., Shevchenko, M.A., Pasyukov, D.V., ...Chernyshev, V.M., Ananikov, V.P. Catalysis Science and Technology, 2020, 10(5), p. 1228–1247.
Palladium-catalyzed synthesis of pyrimido[5’,4’:3,4]pyrrolo[1,2-f]phenanthridine-12,14(11H,13H)-diones and related compounds Shevchenko, M.A., Tkachenko, Y.N., Astakhov, A.V., ...Kravchenko, O.A., Chernyshev, V.M. Russian Chemical Bulletin, 2018, 67(9), p. 1684–1694.
Successive alkylation of PtII by RI to form bis-organoplatinum(IV) derivatives as key steps for cross-electrophile coupling Khazipov, O.V., Krasnyakova, T.V., Nikitenko, D.V., ...Khomutova, E.V., Mitchenko, S.A. Journal of Organometallic Chemistry, 2018, 867, p. 333–341.

Chernenko Andrey Yurievich

Post:

Engineer of the Research Institute "Nanotechnology and New Materials"

Education:

2010-2015: student, Department of "Technology of inorganic and Organic substances, specialty "Chemical technology of organic substances", SRSPU (NPI).
2015-2019: postgraduate student, specialty "Chemical technology", SRSPU (NPI).

Qualification:

2015-2019: postgraduate student, specialty "Chemical technology", SRSPU (NPI)

Professional activity:

from 2014 to the present: laboratory of organic synthesis

Scientific interests:

Organic chemistry, metal complex catalysis, N-heterocyclic carbenes, chemistry of heterocyclic compounds

Project manager:

RSF, grant 22-23-00380 "Development of new methods of catalytic functionalization of 1,2,4-triazoles for the synthesis of biologically active compounds", completion dates 2022-2023

Executor in projects:

2014-2016: RSF, grant 14-23-00078 "New catalytic systems and processes of selective synthesis and processing of multifunctional organic substances".
2017-2018: RSF, grant 14-23-00078 (extension) "New catalytic systems and processes of selective synthesis and processing of multifunctional organic substances".
2016-2019: RFBR, grant 16-29-10786 "Catalytic systems based on transition metal complexes with N-heterocyclic carbenes: degradation processes of complexes and their effect on catalytic activity in cross-combination reactions".
2017-2018: RFBR grant 17-33-50047 "Studies of transformation processes of complexes with N-heterocyclic carbenes in catalytic reactions by NMR and high-resolution mass spectrometry".
2019-2022: RSF, grant 19-73-10100 "Development of effective catalysts based on nickel and palladium complexes with N-heterocyclic carbenes (NHC) in carbon-heteroatom bond formation reactions for the synthesis of practically important molecules".

Major publications:

Chernenko A. Yu., Astakhov A. V., Kutyrev V. V., Gordeev E. G., Burykina J. V., Minyaev M. E., Khrustalev V. N., Chernyshev V. M., Ananikov V. P. «Stabilization of the Pd-NHC framework with 1,2,4-triazol-5-ylidene ligands toward decomposition in alkaline media», Inorganic Chemistry Frontiers, 2021, 8, 3382-3401. https://doi.org/10.1039/d1qi00453k
Pasyukov D. V., Chernenko A. Yu., Shepelenko K. E. Kutyrev V. V., Khrustalev V.N., Chernyshev V. M. «3-Amino-1,2,4-triazolium salts as NHC-proligands: synthesis and postmodification of a new type of amino-functionalized Pd/NHC complexes», Mendeleev Communications, 2021, 31, 176-178. http://dx.doi.org/10.1016/j.mencom.2021.03.010
Khazipov O. V., Shevchenko M. A., Pasyukov D. V., Chernenko A. Yu., Astakhov A. V., Tafeenko V. A., Chernyshev V. M., Ananikov V. P. «Preventing Pd–NHC bond cleavage and switching from nano-scale to molecular catalytic systems: amines and temperature as catalyst activators», Catalysis Science & Technology, 2020, 10, 1228-1247. https://doi.org/10.1039/C9CY02041A
Chernyshev V. M., Khazipov O. V., Shevchenko M. A., Chernenko A. Yu., Astakhov A. V., Eremin D. B., Pasyukov D. V., Kashin A. S. and Ananikov V. P. «Revealing the unusual role of bases in activation/deactivation of catalytic systems: O-NHC coupling in M/NHC catalysis», Chemical Science, 2018, 9, 5564-5577. https://doi.org/10.1039/C8SC01353E
Khazipov O. V., Shevchenko M. A., Chernenko A. Yu., Astakhov A. V., Pasyukov D. V., Eremin D. B., Zubavichus Y. V., Khrustalev V. N., Chernyshev V. M., and Ananikov V. P. « Fast and Slow Release of Catalytically Active Species in Metal/NHC Systems Induced by Aliphatic Amines», Organometallics, 2018, 37, 1483-1492. https://doi.org/10.1021/acs.organomet.8b00124
Chernenko A. Yu., Pasyukov D. V., Astakhov A. V., Tafeenko V. A., Chernyshev V. M. «Reactions of Pd-PEPPSI complexes with protic acids», Russian Chemical Bulletin, International Edition, 2018, 7, 1196-1201. https://doi.org/10.1007/s11172-018-2201-9
Chernenko A. Yu., Astakhov A. V., Pasyukov D. V., Dorovatovskii P. V., Zubavichus Ya. V., Khrustalev V. N., Chernyshev V. M. «Pd-PEPPSI complexes based on 1,2,4-triazol-3-ylidene ligands as efficient catalysts in the Suzuki—Miyaura reaction», Russian Chemical Bulletin, International Edition, 2018, 67, 79-84. https://doi.org/10.1007/s11172-018-2040-8
Astakhov A. V., Khazipov O.V., Chernenko A. Yu., Pasyukov D. V., Kashin A. S., Gordeev E. G., Khrustalev V. N., Chernyshev V. M., Ananikov V. P., «A new mode of operation of Pd-NHC systems studied in a catalytic Mizoroki-Heck reaction», Organometallics, 2017, 36, 1981-1992. https://doi.org/10.1021/acs.organomet.7b00184
Pyatakov D. A., Sokolov A. N, Astakhov A. V., Chernenko A. Yu., Fakhrutdinov A. N., Rybakov V. B., Chernyshev V. V., Chernyshev V. M. «Diversity oriented synthesis of polycyclic heterocycles through the condensation of 2-amino[1,2,4]triazolo[1,5-a]pyrimidines with 1,3-diketones». The Journal of Organic Chemistry, 2015, 80, 10694-10709. https://doi.org/ 10.1021/acs.joc.5b01908

SCOPUS

Soliev Safarmurod Bakhtiyorovich

Post:

Engineer of the SRI «Nanotechnologies and new materials»

Major publications:

Complexes LNi(Cp)X with alkylamino-substituted N-heterocyclic carbene ligands (L) and their catalytic activity in the Suzuki—Miyaura reaction Chesnokov, V.V., Shevchenko, M.A., Soliev, S.B., Tafeenko, V.A., Chernyshev, V.M. Russian Chemical Bulletin, 2021, 70(7), стр. 1281–1289
Ni/NHC catalysis in C-H functionalization using air-tolerant nickelocene and sodium formate for: In situ catalyst generation Khazipov, O.V., Shepelenko, K.E., Pasyukov, D.V., ...Chernyshev, V.M., Ananikov, V.P. Organic Chemistry Frontiers, 2021, 8(11), стр. 2515–2524
Different effects of metal-NHC bond cleavage on the Pd/NHC and Ni/NHC catalyzed α-arylation of ketones with aryl halides Shepelenko, K.E., Soliev, S.B., Galushko, A.S., Chernyshev, V.M., Ananikov, V.P. Inorganic Chemistry Frontiers, 2021, 8(6), стр. 1511–1527
Metal-ligand bond dissociation energies in the Ni, Pd, and Pt complexes with N-heterocyclic carbenes: effect of the oxidation state of the metal (0, +2) Astakhov, A.V., Soliev, S.B., Chernyshev, V.M. Russian Chemical Bulletin, 2020, 69(11), стр. 2073–2081
Nickel(ii) N-heterocyclic carbene complexes as efficient catalysts for the Suzuki—Miyaura reaction Soliev, S.B., Astakhov, A.V., Pasyukov, D.V., Chernyshev, V.M. Russian Chemical Bulletin, 2020, 69(4), стр. 683–690
Relative stabilities of M/NHC complexes (M = Ni, Pd, Pt) against R-NHC, X-NHC and X-X couplings in M(0)/M(ii) and M(ii)/M(iv) catalytic cycles: A theoretical study Astakhov, A.V., Soliev, S.B., Gordeev, E.G., Chernyshev, V.M., Ananikov, V.P. Dalton Transactions, 2019, 48(45), стр. 17052–17062

Kutyrev Vadim Vladimirovich

Post:

Assistant of the Department of Chemical Technologies

Education:

2016 - 2020: student (bachelor) in the field of 18.03.01 ‘’Chemical Technology’’, Department of Chemical Technologies, SRSPU (NPI).
2020 - 2022: student (master) in the field of 18.04.01 ‘’Chemical Technology’’, Department of Chemical Technologies, SRSPU (NPI).
2022 - to the present: postgraduate student in scientific specialty 2.6.10. ‘’Technology of organic substances’’, SRSPU (NPI).

Qualification:

2020: bachelor in the field of 18.03.01 ‘’Chemical Technology’’, Department of Chemical Technologies, SRSPU (NPI), diploma with honors.
2022: master in the field of 18.04.01 ‘’Chemical Technology’’, Department of Chemical Technologies, SRSPU (NPI), diploma with honors.

Professional activity:

2019 - 2020: laboratory assistant of the RI ‘’Nanotechnologies and new materials’’.
2020 - 2021: research assistant of the RI ‘’Nanotechnologies and new materials’’.
2021 - 2022: engineer of the RI ‘’Nanotechnologies and new materials’’.
2022 - 2022: 1^st category engineer of the RI ‘’Nanotechnologies and new materials’’.
2022 - to the present: assistant at the Department of Chemical Technologies of SRSPU (NPI).

Scientific interests:

Organic chemistry, chemistry of heterocyclic compounds, N-heterocyclic carbens, metal complex catalysis

Participation in projects:

2019 - 2022: RSF, grant No. 19-73-10100 ‘’Development of effective catalysts based on nickel and palladium complexes with N-heterocyclic carbenes (NHC) in reactions of formation of carbon-heteroatom bonds for the synthesis of practically important molecules’’.
2020 - 2022: RSF, grant No. 19-73-20085 ‘’Highly efficient catalytic systems for C-H functionalization processes based on transition metal complexes with N-heterocyclic carbenes’’.
2020 - 2020: scientific project No. 2019-0990 ‘’Catalytic processing of carbon-containing materials into synthetic motor fuels, isoparaffin and poly-alpha-olefin oils’’.
2022 - 2023: RL ‘’New composite and functional materials with special properties’’.
2023 - to the present: RSF, grant No. 23-73-00088 ‘’Ionizable C- and N-donor ligands for metal complex catalysis’’.
2023 – to the present: RSF, grant No. 23-23-00399 ‘’Heteroatom-doped carbon materials from humins for (electro)catalytic synthesis of organic substances’’.

Major publications:

Theoretical and experimental study of prototropic tautomerism of C-amino-3(5)R-1,2,4-Triazoles Chernenko A. Yu., Pasyukov D.V., Ranniy G.S., Soliev S.B., Kutyrev V.V., Astakhov A.V., Chernyshev V.M. Izvestiya vuzov. Severo-kavkazskiy region. Technical science. – 2019 - №1 (201). DOI: 10.17213/0321-2653-2019-1-82-87
3-Amino-1, 2, 4-triazolium salts as NHC-proligands: synthesis and postmodification of a new type of amino-functionalized Pd/NHC complexes Pasyukov D. V., Chernenko A. Y., Shepelenko K. E., Kutyrev V. V., Khrustalev V. N., Chernyshev V. M. Mendeleev Communications, 31(2), 176-178. DOI: 10.1016/j.mencom.2021.03.010
Stabilization of the Pd–NHC framework with 1,2,4-triazol-5-ylidene ligands toward decomposition in alkaline media Chernenko A. Y., Astakhov A. V., Kutyrev V. V., Gordeev E. G., Burykina J. V., Minyaev M. E., Ananikov V. P. Inorganic Chemistry Frontiers, 8(13), 3382-3401. DOI: 10.1039/D1QI00453K
Selective Buchwald–Hartwig arylation of C-amino-1,2,4-triazoles and other coordinating aminoheterocycles enabled by bulky NHC ligands and TPEDO activator Astakhov A. V., Chernenko A. Y., Kutyrev V. V., Ranny G. S., Minyaev M. E., Chernyshev V. M., Ananikov V. P. Inorganic Chemistry Frontiers, 10(1), 218-239. DOI: 10.1039/D2QI01832B

SCOPUS

Voloshina Elena Nikolaevna

Post:

Research assistant of the RI «Nanotechnologies and new materials»

Lavrentiev Igor Vyacheslavovich

Post:

Laboratory assistant of the research laboratory «New composite and functional materials with special properties»

Education:

2016 - 2021 – student of the Donetsk National University.
2021 – to the present – postgraduate student of the SRSPU (NPI) named after M. I. Platov.

Professional activity:

Since 2021 employee of the laboratory of organic synthesis

Scientific interests:

Organic chemistry

Gnatyuk Irina Gennadievna

Post:

Laboratory assistant of the research laboratory «New composite and functional materials with special properties»

Education:

2013-2017: student of the Donetsk Technical College of Chemical Technology and Pharmacy. Department: «Analytical quality control of chemical compounds».
2017-2021: student of the Donetsk National University, Department: «Non-organic chemistry».
2021 – to the present: postgraduate student, Department of «Chemical Technology», SRSPU (NPI).

Professional activity:

2021 – to the present – laboratory assistant of the research laboratory «Nanotechnologies and new materials»

Scientific interests:

Organic chemistry, heterocyclic compounds, metal complex catalysis

Participation in projects:

2021 – to the present – RSF grant: 22-23-00304 «Water-soluble M/NHC catalysts based on hydrophilic ligands of the imidazole row»

Pyatachenko Anastasia Sergeevna

Contacts:

Телефон: +79198950304
Email: anastasiapatacenko790@gmail.com

Post:

Техник лаборатории “Катализаторы и технологии переработки углеродсодержащих материалов”

Education:

2017-2021 г.г: студент, Химический факультет, ДонНУ (Донецкий национальный университет)

Qualification:

2021 г. – специалитет (Химик. Преподаватель химии.)

Professional activity:

07.2022 - по настоящие время техник в лаборатории “Катализаторы и технологии переработки углеродсодержащих материалов”

Scientific interests:

Металлокомплексный катализ

Laboratory team