Contacts:
Phone: +79289661653
Email: samit_RPt@mail.ru
Post:
Leading researcher of the Research Institute "NTNM"
Education:
- 1973 – 1979: Moscow Institute of Physics and Technology, Faculty of Molecular and Chemical Physics, Moscow.
- 1980 – 1982: Postgraduate course of the Institute of Physical and Organic Chemistry and Carbon Chemistry of the Academy of Sciences of the USSR, Donetsk.
- 1996 – 1999: Doctorate of the Institute of Organoelement Compounds named after A.N. Nezmeyanov RAS, Moscow
Qualification:
- 1983: Defense of the candidate's dissertation
- 2003: Defense of the doctoral dissertation “Alkyl and s-vinyl derivatives of platinum acid complexes and catalytic reactions with their participation”
- 2008: Academic title of professor in the specialty 02.00.04 – “Physical chemistry", organometallic chemistry;
Professional activity:
- 1986 – 1989: Researcher at the Institute of Physico-Organic Chemistry and Carbon Chemistry of the National Academy of Sciences of Ukraine, Donetsk
- 1982 – 1986: Researcher at the Institute of Physico-Organic Chemistry and Carbon Chemistry of the National Academy of Sciences of Ukraine, Donetsk.
- 1989 – 2004: Senior Researcher of the Institute of Physico and Organic Chemistry and Carbon Chemistry of the National Academy of Sciences of Ukraine, Donetsk.
- 2004 – 2013: Leading Researcher at the Institute of Physical and Organic Chemistry and Carbon Chemistry of the National Academy of Sciences of Ukraine, Donetsk
- since 2013: Head of the Department of Electrophilic Reactions Research at the Institute of Physical and Organic Chemistry and Carbon Chemistry of the National Academy of Sciences of Ukraine, Donetsk.
Scientific interests:
Homogeneous metal-complex catalysis, mechanochemistry, heterogeneous catalysis on mechanoactivated catalysts. To develop methods for the synthesis of previously unavailable monoalkyl and -vinyl derivatives of simple platinum acid complexes, their reactivity was studied and on this basis new catalytic cycles were constructed with the participation of these organo-platinum compounds as intermediates.
Major publications:
- Khazipov O. V., Solvent-specific reduction of Na2PtI6 in acetone / Khazipov O. V., Merzlikina M. A., Nikytenko D. V., Khomutova E. V., Krasnyakova T. V., Mitchenko S. A. // Russian Journal of General Chemistry. ‒ 2017. ‒ T. 87, № 1. ‒ C. 128-131.
- Khazipov O. V., Catalytic etherification of alcohols in Shilov system: C-O versus C-H bond activation / Khazipov O. V., Nykytenko D. V., Krasnyakova T. V., Vdovichenko A. N., Fuentes Frias D. A., Mitchenko S. A. // Journal of Molecular Catalysis A: Chemical. ‒ 2017. ‒ T. 426. ‒ C. 490-498.
- Krasnyakova T. V., Catalytic hydrochlorination of acetylene on PdCl2/C supported catalysts: Kinetic isotopic effect of HCl/DCl, stereoselectivity, and mechanism / Krasnyakova T. V., Nikitenko D. V., Khomutova E. V., Mitchenko S. A. // Kinetics and Catalysis. ‒ 2017. ‒ T. 58, № 5. ‒ C. 533-540.
- Savostyanov A. P., Synthesis of Low-Pour-Point Diesel Fuel in the Presence of a Composite Cobalt-Containing Catalyst / Savostyanov A. P., Narochnyi G. B., Yakovenko R. E., Saliev A. N., Sulima S. I., Zubkov I. N., Nekroenko S. V., Mitchenko S. A. // Petroleum Chemistry. ‒ 2017. ‒ T. 57, № 12. ‒ C. 1186-1189.
- Savostyanov A. P., Industrial catalyst for the selective Fischer–Tropsch synthesis of long-chain hydrocarbons / Savostyanov A. P., Yakovenko R. E., Narochnyi G. B., Bakun V. G., Sulima S. I., Yakuba E. S., Mitchenko S. A. // Kinetics and Catalysis. ‒ 2017. ‒ T. 58, № 1. ‒ C. 81-91.
- Savostyanov A. P., Unexpected increase in C5+ selectivity at temperature rise in high pressure Fischer-Tropsch synthesis over Co-Al2O3/SiO2 catalyst / Savostyanov A. P., Yakovenko R. E., Narochniy G. B., Sulima S. I., Bakun V. G., Soromotin V. N., Mitchenko S. A. // Catalysis Communications. ‒ 2017. ‒ T. 99. ‒ C. 25-29.
- Savost'yanov A. P., The impact of Al2O3 promoter on an efficiency of C5+ hydrocarbons formation over Co/SiO2 catalysts via Fischer-Tropsch synthesis / Savost'yanov A. P., Yakovenko R. E., Sulima S. I., Bakun V. G., Narochnyi G. B., Chernyshev V. M., Mitchenko S. A. // Catalysis Today. ‒ 2017. ‒ T. 279. ‒ C. 107-114.
- Khazipov O. V., Successive alkylation of PtII by RI to form bis-organoplatinum (IV) derivatives as key steps for cross-electrophile coupling / Khazipov O. V., Krasnyakova T. V., Nikitenko D. V., Merzlikina M. A., Khomutova E. V., Mitchenko S. A. // Journal of Organometallic Chemistry. ‒ 2018. ‒ T. 867. ‒ C. 333-341.
- Savostyanov A. P., Enhancement of the Fischer–Tropsch process for producing long-chain hydrocarbons on a cobalt–alumina–silica gel catalyst / Savostyanov A. P., Narochnyi G. B., Yakovenko R. E., Mitchenko S. A., Zubkov I. N. // Petroleum Chemistry. ‒ 2018. ‒ T. 58, № 1. ‒ C. 76-84.
- Savostyanov A. P., Supported Bifunctional Cobalt Catalysts for CO and H2 Conversion to Fuel Fractions of Hydrocarbons / Savostyanov A. P., Yakovenko R. E., Saliev A. N., Narochnyi G. B., Mitchenko S. A., Zubkov I. N., Soromotin V. N., Kirsanov V. A. // Petroleum Chemistry. ‒ 2018. ‒ T. 58, № 5. ‒ C. 434-443.
- Smirnova N. V., Selective Oxidation of 5-(Hydroxymethyl) furfural to Furan-2,5-dicarbaldehyde with Sodium Nitrite in Phosphoric Acid / Smirnova N. V., Klushin V. A., Bezbozhnaya T. V., Khomutova E. V., Lobachev V. L., Mitchenko S. A. // Russian Journal of Organic Chemistry. ‒ 2018. ‒ T. 54, № 3. ‒ C. 414-418.
- Savostyanov A. P., Bifunctional CO/SiO2-Fe-ZSM-5-Al2O3 catalysts for synthesis of hydrocarbons of engine fractions / Savostyanov A. P., Yakovenko R. E., Narochny G. B., Nepomnyashchikh E. V., Mitchenko S. A. // ChemChemTech. ‒ 2019. ‒ T. 62, № 8. ‒ C. 139-146.
- Krasnyakova T. V., Catalytic Hydromethoxylation of Acetylene over Pre-Activated K2PdCl4 / Krasnyakova T. V., Nikitenko D. V., Khazipov O. V., Mitchenko S. A. // Kinetics and Catalysis. ‒ 2020. ‒ T. 61, № 6. ‒ C. 879-885.
- Krasnyakova T. V., Mechanisms of the Catalytic Hydrochlorination of Acetylene: Active Sites, Isotope Effects, and Stereoselectivity / Krasnyakova T. V., Nikitenko D. V., Mitchenko S. A. // Kinetics and Catalysis. ‒ 2020. ‒ T. 61, № 1. ‒ C. 58-79.
- Krasnyakova T. V., Effect of Mechanochemical Pretreatment on the Photocatalytic Activity of Bismuth Ferrite / Krasnyakova T. V., Yurchilo S. A., Morenko V. V., Nosolev I. K., Glazunova E. V., Khasbulatov S. V., Verbenko I. A., Mitchenko S. A. // Kinetics and Catalysis. ‒ 2020. ‒ T. 61, № 3. ‒ C. 384-389.
- Savostyanov A. P., Deactivation of Co-Al2O3/SiO2 Fischer–Trospch Synthesis Catalyst in Industrially Relevant Conditions / Savostyanov A. P., Eliseev O. L., Yakovenko R. E., Narochniy G. B., Maslakov K. I., Zubkov I., Soromotin V. N., Kozakov A. T., Nicolskii A. V., Mitchenko S. A. // Catalysis Letters. ‒ 2020. ‒ T. 150, № 7. ‒ C. 1932-1941.
- Savostyanov A. P., Deactivation of a Commercial Co–Al2O3/SiO2 Catalyst in Fischer–Tropsch Synthesis under High-Pressure and Gas Recycling Conditions / Savost’yanov A. P., Yakovenko R. E., Narochnyi G. B., Zubkov I. N., Sulima S. I., Soromotin V. N., Mitchenko S. A. // Petroleum Chemistry. ‒ 2020. ‒ T. 60, № 1. ‒ C. 81-91.
- Ulyankina A., Selective photocatalytic oxidation of 5-HMF in water over electrochemically synthesized TiO2 nanoparticles / Ulyankina A., Mitchenko S., Smirnova N. // Processes. ‒ 2020. ‒ T. 8, № 647.
- Yakovenko R. E., Preliminary evaluation of a commercially viable Co-based hybrid catalyst system in Fischer-Tropsch synthesis combined with hydroprocessing / Yakovenko R. E., Savostyanov A. P., Narochniy G. B., Soromotin V. N., Zubkov I. N., Papeta O. P., Svetogorov R. D., Mitchenko S. A. // Catalysis Science and Technology. ‒ 2020. ‒ T. 10, № 22. ‒ C. 7613-7629.
- Yakovenko R. E., Hybrid Catalyst for the Selective Synthesis of Fuel Range Hydrocarbons by the Fischer–Tropsch Method / Yakovenko R. E., Zubkov I. N., Savost’yanov A. P., Soromotin V. N., Krasnyakova T. V., Papeta O. P., Mitchenko S. A. // Kinetics and Catalysis. ‒ 2021. ‒ T. 62, № 1. ‒ C. 172-180.
- Soromotin V.N., Reasons for the rapid deactivation of the cobalt catalyst in the high-throughput Fischer–Tropsch synthesis of C19+ hydrocarbons / V.N. Soromotin, R.E. Yakovenko, A.V. Medvedev, S.A. Mitchenko // Kinetics and catalysis. - 2021. - T. 62, No. 6. - C. 811-820.
- Zubkov I.N., Production of Alcohols and Olefins from CO and H2 on a Cobalt Catalyst at High Pressures and in the Gas Circulation Mode / I.N. Zubkov, V.N. Soromotin, A.P. Savost’yanov, S.A. Mitchenko, R.E. Yakovenko // Kinetics and Catalysis – 2022. – Vol. 63, No.2. – pp. 218-225. DOI: 10.1134/S0023158422020148
- Krasnyakova T.V., Catalysis of Electrophilic C(sp2)–C(sp2) Coupling by Platinum(II) Iodide Complexes / T.V. Krasnyakova, D.V. Nikitenko, V.V. Morenko, S.A. Mitchenko // Kinetics and Catalysis. – 2022. – Vol. 63, No. 3. – pp. 270–278. DOI: 10.1134/S0023158422030053
Links to identifiers:
Scopus ID: 7004432184
Web of Science ID: D-6860-2015
ORCID: 0000-0003-3562-1256
