RNF 22-23-00304
Based on the obtained data on the catalysis of certain model reactions, conclusions will be drawn about the possibility of recommending appropriate catalysts and reaction conditions for use in synthesis, including in the technological process.
EXPECTED PROJECT RESULTS:
Methods of synthesis of new proligands of a number of imidazolium containing functional group– halogen- (acyloxy-)methyl and trialkylammonio- (1-pyridinio-, 1-azolio-)methyl.
Based on these proligands, methods for obtaining water-soluble M/NHC complexes (M = Pd, Ru, Ni, Cu) of a new type will be developed, data on their catalytic activity in a number of cross-combination and addition reactions will be obtained.
New effective ones will be developed Shevchenko M.A. beer catalytic systems for conducting metal-catalyzed carbon-carbon bond formation reactions in an aqueous medium.